1.

Equal weights of phosphorusand oxygenare heated in a closed vessel producing P_(2)O_(3) and P_(2)O_(5) in a 1 : 1mole ratio. Ifthe limitingcomponent is exhausted, findwhichcomponentand alsowhatfraction of it is left over.

Answer»

Solution :As1 mole each of `P_(2) O_(3) and P_(2) O_(5)` is formed, the mole ratio of thereacting P and O ATOMSIS 4 : 8 or 1 : 2 As the givenweights of phosphorus and oxygen are same, say w g,their
MOLES of ATOMS are `(omega)/(31) and (omega)/(16)` respectively.
`:.` 2 moles of O combine WITH1 mole of P.
`:. (omega)/(16)` moles of O combine with `(omega)/( 32)`moles of P.
Sophosphorous is left over and
moles of Premaining `= (omega)/( 31) - (omega)/( 32)`
`:.`fractionof P left over`=(((omega)/(31)-(omega)/(32)))/((omega)/(31))= (1)/(32)or 3 . 125 %`


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