Ethanol cannot be dried over anhydrous CaCl_(2) because
Answer»
`CaCl_(2)` DISSOLVES in it it forms a solid alcoholate i.e. `CaCl_(2) 3C_(2)H_(2)OH` it is not a good dehydrating agent it reacts with `CaCl_(2)` to FORM `H_(2)` gas.
Solution :Ethanol forms a solid alcoholate, ie `CaCl_(2).3C_(2)H_(5)OH`