Saved Bookmarks
| 1. |
Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements. |
|
Answer» both the compounds form same product on treatment with alcoholic KOH `UNDERSET("Ethylene CHLORIDE")(ClCH_(2))-CH_(2)Cl"or"underset("Ethylidene chloride")(CH_(3)CHCl_(2)) underset(-2" HCl")overset("Alc. KOH")to underset("Acetylene")(HC-=CH)` (b) both the compounds form different products on treatment with aq. NaOH. `underset("Ethylene chloride")({:(CH_(2)Cl,),(|,),(CH_(2)Cl,):})overset(Aq." "NaOH)to underset("Ethylene glycol")({:(CH_(2)OH,),(|,),(CHCl_(2),):}) overset(Aq.NaOH)to {:(CH_(3),),(|,),(CH(OH)_(2),):}underset(-H_(2)O)to underset("Acetaldehyde")({:(CH_(3),),(|,),(CHO,):})` (c) Both the compounds form same product, i.e., ethane on reduction. `ClCH_(2)CH_(2)Cl` or `CH_(3)CHCl_(2) overset("Reduction")to underset("Ethane")(CH_(3)-CH_(3))+2HCl` (d) Both the comounds are not optically active. thus, options (a) and (c) are correct. |
|