1.

Examine the given defective crystal and {:(A^(+),B^(-),A^(+),B^(-),A^(+)),(B^(-),0,B^(-),A^(+),B^(-)),(A^(+),B^(-),A^(+),0,A^(+)),(B^(-),A^(+),B^(-),A^(+),B^(-)):} Answer the following questions : (i) What type of stoichiometirc defect is shown by the crystal ? (ii) How is the density of the crystal affected by this defect ? (iii) What type of ionic substances show such defect ?

Answer»

Solution :(i) SCHOTTKY DEFECT.
(ii) DECREASES.
(iii) Alkali METAL halides/Ionic substances having almost similar SIZE of cations and anions (NaCl/KCl).


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