1.

Explain about the hydrolysis of salt of strong acid and a strong base with a suitable example.

Answer»

Solution :(i) Let us consider the neutralisation reaction between NAOH and `HNO_3` to give water
`NaOH(aq) +HNO_3(aq) to NaNO_3 (aq)+H_2O_l`
(ii) The salt `NaNO_3` completely dissociated in water to produce `Na^(+) and NO_3^(-)` ions
`NaNO_(aq) to^(H_2O) Na^(+) (aq) +NO_3^(-) (aq)`
(iii) water dissociates to a small extent as
`H_2O_l leftrightarrow H^(+) (aq)+OH^(-) (aq)`
Since `[H^+]=[OH^-]` water is neutral.
(iv) `NO_3^(-)` ion is the conjugate base of strong acid `HNO_3` and HENCE it has no tendency to react with `H^+`
(V) Similarly `Na^+` is the conjugate acid of the strong base NaOh and it has no tendency to react with `Oh^-`
(vi) It means that there is no hydrolysis, In such case `[H^+]=[OH^-]`, ph is MAINTAINED and there fore the solution is neutral.


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