1.

Explain linkage isomerism with example.

Answer»

SOLUTION :Compounds having the same molecular formula but differ in the MODE of attachment of a ligand to the central metal atom/ion.
OR
A type of structure in which isomers differ in the ligating atom of AMBIDENT ligand.
OR
A type of structural isomerism that occurs when more than one type of atom in a monodentate ligand acts as a donor atom.
`[Co NO_2 (NH_3)_5] Cl_2 ` & `[Co ONO (NH_3)_5] Cl_2` or its COMPLEX ions.
OR
`[Cr SCN (H_2 O)_5)^(2+) ` & `[Cr NCS (H_2 O)_5]^(2+)`


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