Explain linkage isomers with NO2- group as a ligand. – InterviewSolution

InterviewSolution

1.

Explain linkage isomers with NO2- group as a ligand.

Answer»

(1) Nitro group (NO₂^-) is an ambidentate ligand. NO₂^- group may link to central metal atom, through N or O.

(2) The two linkage isomers are,

[CI : → Ag ← : NO₂^-] and [CI : → Ag ← O-NO]^-

Choloronitroargentate(I) ion and Chloronitritoargentate(I) ion

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