1.

Explain mutarotation in glucose.

Answer»

Solution :The specific ROTATION of pure `alpha` and `beta-(D)` glucose are `112^(@)` & `18.7^(@)` RESPECTIVELY. However, when pure form of any ONE of these sugars dissolved in water, slow interconversion of `alpha`-D glucose and `beta`-D glucose via open chain form until EQUILIBRIUM is established giving constant specific rotation`+ 53^(@)`. This phenomenon is called MUTAROTATION.


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