1.

Explain the preparation of potassium permanganate from MnO_(2) Write the balanced chemical equations for the reactions involved.

Answer»

Solution :Potassium PERMANGANATE is prepared by the fusion of `MnO_(2)`with an alkali METAL hydroxide and an OXIDISINGAGENT like `KNO_(3)`. This RESULTS in the formation of the dark green `K_(2)MnO_(4)`which disproportionates in a neutral or acidic solution to give potassium permanganate.
`2MnO_(2) +4KOH +O_(2)to 2K_(2)MnO_(4) +2H_(2)O`
`3K_(2)MnO_(4) +4H^(+)to 2KMnO_(4) +MnO_(2) +2H_(2)O +4K^(+)`


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