1.

Explain the reaction of ammonia with chlorine and chlorides different conditions.

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Solution :(i) Explain the reacts with chlorine and chlorides to give ammonium CHLORIDE as a final product.
(II) The reactions are different under different conditions as given below.
(iii) With excess ammonia
`2NH_(3)+3Cl_(2) rarr N_(2)+6HCl`
`6HCl+6NH_(3) rarr 6NH_(4)Cl`
(IV) With excess of chlorine ammonia reacts to give nitrogen trichloride, anexplosive substance.
With excess of chlorine ammonia reacts to give nitrogen trichloride, an EXPLOSIVE substance.
`2NH_(3)+6Cl_(2) rarr 2NCl_(3)+6HCl`
`2NH_(3)(g)+HCl(g)rarrNH_(4)Cl(s)`


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