1.

Explain the role of : Carbon monoxide in the purification of nickel.

Answer»

SOLUTION :Carbon monoxide reacts with nickel to form nickel tetracarbonyl.
`{:(Ni+4CO overset(330-350K)(to)Ni (CO)_(4)),("Nickel tetracarbonyl "):}`
The IMPURITIES remain unreacted. `Ni(CO)_(4)` on heating to a higher temperature DECOMPOSES to GIVE pure nickel.
`Ni(CO)_(4) overset(450-470K)(to)Ni+ 4CO`.


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