1.

Explain the significance of Ellingham diagram.

Answer»

SOLUTION :(1) Ellingham diagram is obtained by plotting standard free energy change `DeltaG^(@)` for the formation of oxides of elements.
(2) The oxides of elements which are very stable with high negative values of `DeltaG^(@)` are at the LOWER side of the Ellingham diagram.
(3) The positive slope of lines indicate that the stability of metal oxides decreases due to increase in `DeltaG^(@)` with the increase in temperature and they can be reduced easily.

(4) The sudden change in the graphs and slopes indicates a phase change from solid to liquid or from liquid to vapour.
(5) (5) The Ellingham diagram enables to select a SUITABLE REDUCING agent for the reduction of given metal oxide. An element can reduce the oxide of another element above it in Ellingham diagram.


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