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| 1. | Explain the various processes of thermodynamics and work done in these processes. | 
| Answer» Every equilibrium state of a thermodynamical system is completely described by specific values of some macroscopic variables. If in a thermodynamic system, variables like temperature (T), pressure (P), volume (V), etc. changes with time, then the process is called thermodynamical process. There are various types of thermodynamical processes : (i) Isothermal process : Isothermal process takes place in any type of system that regulates the temperature. In the thermodynamic analysis of chemical reactions, it is first analyzed what happens under isothermal conditions. In an isothermal process, the internal energy of an ideal gas is constant. This is due to the fact that there are no intermolecular forces in an ideal gas. In the isothermal compression of a gas, there is work done on the system to decrease the volume and increase the pressure. Doing work on the gas, can increase the internal energy and increase the temperature. For constant temperature, energy must leave the system. For an ideal gas, the amount of energy entering the environment is equal to the amount of work done on the gas, as the internal energy does not vary. (ii) Isochoric process : (iii) Isobaric process : (iv) Adiabatic process : A process in which transfer of heat is not involved in the system, so that Q = 0, is called an adiabatic process. For example, the compression of a gas within an engine’s cylinder is assumed to take place so fast that on the time scale of the process of compression, little energy of the system can be transferred out as heat. Essential conditions for an adiabatic process : 
 (v) Cyclic process : | |