1.

Explain why compounds of Cu^(2+) are coloured but those of Zn^(2+) are colourless.

Answer»

Solution :Cu (Z = 29) Electronic configuration is [Ar]`3d^(10) 4s^(1)`
`Cu^(2+)` : Electronic configuration is [Ar]`3d^(9)`.
In `Cu^(2+)` promotion of electrons take place in outer d-orbital by the absorption of light form visible region involves d - d transition. Due to this `Cu^(2+)` compounds are coloured. Where in `Zn^(2+)` electronic configuration is `[Ar]3d^(10)`. It has completely FILLED d-orbital. So there is no chance of d-d transition. So `Zn^(2+)` compounds are COLOURLESS.


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