1.

Explainthe variationin E_(m^(2+))^(0) //M 3dseries .

Answer»

SOLUTION :(I ) in 3dseriesas we movefrom Ti to Znthe standardreductionpotential `[(E_(0))/(M)]`
valueisapproachingtowardslessnegativevalueand copperhas a positivereductionpotential i.E.,elementalcopperis morestablethan `Cu^(2+)`
(ii) Thereare twodeviationsIn the generaltrendsshowthat `[(E_(m^(2+))^(0))/(M)]`VALUE formanganese andzincare morenegativethan thhe regulartrend .
(iii)It isdue to extrastability whicharises dueto the half - FILLED`d^(5)` configuration in `MH^(2+)` andcompletelyfilled`d^(10)` configurationin`Zn^(2)`


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