1.

Find the natural vibration frequency and the quasielatic force coefficient of an S_(2) molecule if the wavelength of the red and voilet satellites, closests to the fixed line, in the vibration specturm of Raman scattering are equal to 346.6 and 330.0 nm.

Answer»

Solution :As in the PREVIOUS problem
`omega= pic((1)/(lambda_(V))-(1)/(lambda_(R)))=(pi c(lambda_(R)-lambda_(V)))/(lambda_(R)lambda_(V))= 1.368xx10^(14)rad//s`
The FORCE constant `x` is defined by
`x= mu omega^(2)`
where `mu=` reduced mass of the `S_(2)` MOLECULE.
SUBSTITUTION gives `x=5.01N//cm`


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