1.

Five isomeric para- disubtitutedaromaticcompounds (A) to (E) withmolecularformulaC_(6)H_(6)O_(2)were givefor identification . Basedon the followingobservations findstructureof thecompounds. (i)Both (A) and (B) form a silvermirrorwithTollen'sregent, also(B) givesa positivetest withFeCl_(3)solution . (ii) (C) givespositiveiodoform test .(iii)(D)isreadily extractedin aqueousNaHCO_(3) solution. (iv) (E) on acid hydrolysis gives 1,4- dihydroxybenzene.

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