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Following reactions occur at cathode during the electrolysis of aqueous silver chloride solution: Ag^(+)(aq)+e^(-)toAg(s),E^(@)=+0.80V,H^(+)(aq)+e^(-)to(1)/(2)H_(2)(g),E^(@)=0.00V On the basis of their standard reduction electrode potential (E^(@)) values, which reaction is feasible at the cathode and why? |
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Answer» Solution :Higher the standard REDUCTION potential of a species, more easily it is reduced at the CATHODE. As `Ag^(+)(aq)` has GREATER standard reduction potential, therefore, the reaction that will OCCUR at the cathode is `Ag^(+)(aq)+e^(-)TOAG(s)`. |
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