1.

Following solutions were prepared by mixing different volumes of NAOH of HCL different concentrations. (i) 60 mL (M)/(10) HCI+40 mL (M)/(10) NaOH (ii) 55 mL (M)/(10) HCI+45 mL (M)/(10) NaOH (iii) 75 mL (M)/(5) HCI+25 mL (M)/(5) NaOH (iv) 100 mL (M)/(10) HCI+100 mL (M)/(10) NaOH pH of which one of them will be equal to I?

Answer»

iv
(i)
(II)
(iii)

Solution :No of MOLES of HCL `=0.2 xx 75 xx 10^(-3) = 15 xx 10^(-3)`
No of mole of `NaOH = 0.2 xx 25 xx 10^(-3) = 5 xx 10^(-3)`
No of moles of HCl after mixing `=15 xx 10^(-3) -5 xx 10^(-3)`
`:.` Concentration of HCl `= ("No. of moles of HCl")/("Vol in litre") = (10 xx 10^(-3))/(100 xx 10^(-3)) = 0.1M`
For (iii) solutiion, pH of 0.1 M HCl = `-log_(10) (0.1) = 1`


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