1.

For a chemical reaction A to B , the rate of the reaction is 2 xx 10^(-3) mol dm^(-3) s^(-1) . When the initial concentration is 0.05 mol dm^(-3) . The rate of the same reaction is 1.6 xx 10^(-2) mol dm^(-3) s^(-1) when the initial concentration is 0.1 mol dm^(-3) . The order of the reaction is

Answer»

0
3
1
2

Solution :Let the rate EQUATION for the REACTION be ,
rate = `k [A]^(n)`
where , k = rate constant , n = order of reaction
[A] = concentration of reactant
given , `"rate"_(1) = 2 xx 10^(-3) "mol" dm^(-3) s^(-1)`
`[A_(0)] = 0.05 ` mol `dm^(-3)`
`"rate"_(2) = 1 . 6 xx 10^(-2)` mol `dm^(-3) s^(-1)`
`(A_(0)) = 0.1` mol `dm^(-3)`
`therefore 2 xx 10^(-3) = k [0.05]^(n) "".... (i)`
`1.6 xx 10^(-2) = k[0.1]^(n) "".... (ii)`
DIVIDE (i) by (ii)
`implies (2 xx 10^-3)/(1.6 xx 10^(-2)) = ([0.05]^(n))/([0.1]^(n)) = ([0.05]^(n))/(2^(n)[0.05]^(n))`
`implies (1)/(2^(n)) = (1)/(8) implies n = 3, "" therefore` Order of reaction = 3 .


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