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For a dilute solution containing 2.5 g of a non-volatile, non-electrolytic solute in 100 g of water, the elevation in boiling point at 1 atm pressure is 2^(@)C. Assuming concentration of the solute is much lower than the concentration of the solvent, the vapour pressure (mm of Hg) of the solution is (take K_(b)="0.76 K kg mol"^(-1)) |
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Answer» <P>724 `(p^(@)-p_(s))/(p^(@))=x_(2)=(n_(2))/(n_(1)+n_(2))=(n_(2))/(n_(1))""(" as " n_(2) lt lt n_(1))` `=(w_(2)//M_(2))/(w_(1)//M_(1))` `(760-p_(s))/(760)=(2.5//9.5)/(100//18)=0.047` `or 760-p_(s)=760xx0.047=35.7` `or""p_(s)=724.3mm` |
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