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For the calomel half-cell, `Hg, Hg_(2)Cl_(2)|Cl^(-)(aq)` values of electrode potentials are plotted at different log `[Cl^(-)]`. Variation is represented byA. B. C. D. |
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Answer» Correct Answer - D Half-cell reaction is : `2Hg(l)+2Cl^(-)(aq)rarr Hg_(2)Cl_(2)(s)+2e^(-)` `therefore K (1)/([Cl^(-)]^(2))` `E=E^(@)-(0.0591)/(2)"log"(1)/([Cl^(-)]^(2))` `E=E^(@)+0.0591 log [Al^(-)]` Thus, E increase as `[Cl^(-)]` increases. |
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