1.

For the overall reaction between A and B to yield C and D, two mechanisms are proposed: I. A+BtoAB*toC+D,k_(1)=1xx10^(-5)M^(-1)s^(-1) II. AtoA"*"toE,k_(1)=1xx10^(-4)s^(-1), E+BtoC+d,k_(2)=1xx10^(10)M^(-1)s^(-1) (species with * are short lived) Rate of reaction for mechanism I when concentration of each is 0.1 M, is

Answer»

`1xx10^(-7)MS^(-1)`
`1xx10^(-6)Ms^(-1)`
`1xx10^(-5)Ms^(-1)`
`1xx10^(-4)Ms^(-1)`

Solution :`r_(1)=K_(1)^(1)[A]^(1)[B]^(1)=1xx10^(-5)XX(0.1)^(1)xx(0.1)^(1)=1xx10^(-7)`


Discussion

No Comment Found

Related InterviewSolutions