1.

For the overall reaction between A and B to yield C and D, two mechanisms are proposed: I. A+BtoAB*toC+D,k_(1)=1xx10^(-5)M^(-1)s^(-1) II. AtoA"*"toE,k_(1)=1xx10^(-4)s^(-1), E+BtoC+d,k_(2)=1xx10^(10)M^(-1)s^(-1) (species with * are short lived) Rate of reaction for mechanism II when concentrationof eacn 1 M is

Answer»

`1XX10^(-4)Ms^(-1)`
`1xx10^(10)Ms^(-1)`
`1xx10^(-5)Ms^(-1)`
`1xx10^(-10)Ms^(-1)`

SOLUTION :`r_(2)=K_(1)[A]=1xx10^(-4)xx(1)^(1)=1xx10^(-4)`


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