1.

For the reaction A + B to products , it is observed that : (i) On doubling the initial concentration of A only , the rate of reaction is also doubled and (ii) On doubling the intial concentration of both A and B , there is a change by a factor of 8 in the rate of the reaction The rate of this reaction is given by

Answer»

Rate = `k [A]^(2) [B]`
Rate = ` k [A] [B]^(2)`
Rate = k `[A]^(2) [B]^(2)`
Rate = `k [A] [B]`

Solution :When concentration A is doubled , rate is doubled . Hence order with respect to A is one.
When concentration of both A and B are doubled , rate INCREASED by 8 TIMES hence TOTAL order is 3 .
`THEREFORE`Rate = k `[A]^(1) [B]^(2)`
Order = 1 + 2 = 3 .


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