1.

For weak electrolyte, sudden increase in molar conductance with dilution. Prove this statement.

Answer»

SOLUTION :For a weak electrolyte, at high CONCENTRATION the plot is almost parallel to concentration axis with slight increase in CONDUCTIVITY as the dilution INCREASES.
When the concentration approaches zero, there is a sudden increase in the molar conductance and the curve is a almost parallel to `Lambda_m` axis.
This is due to the fact that the DISSOCIATION of the weak electrolyte increases with the increase in dilution (Ostwald.s dilution law).


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