Four isomeric optically active compounds overset (NaHCO_3) rarr CO_2 (g) (A, B , C, D) (C_4 H_8 O_3) Compound (A) overset (LAH) rarr ( E) (Archiral compound) Compound (B) overset (KMnO_4) underset (or CrO_3) rarr Inert to oxidation. Compound ( C) underset (NaOI//H_3 O^(oplus)) rarr CHI_3 (Yellow ppt.) + Compound (F). Compound (D) is :

Four isomeric optically active compounds overset (NaHCO_3) rarr CO_2 (

1.	Four isomeric optically active compounds overset (NaHCO_3) rarr CO_2 (g) (A, B , C, D) (C_4 H_8 O_3) Compound (A) overset (LAH) rarr ( E) (Archiral compound) Compound (B) overset (KMnO_4) underset (or CrO_3) rarr Inert to oxidation. Compound ( C) underset (NaOI//H_3 O^(oplus)) rarr CHI_3 (Yellow ppt.) + Compound (F). Compound (D) is :
Answer» `(I)` `(II)` `(III)` `(IV)` Solution :(c) (i) From the structures gives in the PROBLEM, `(A)` is `(I)`. SINCE with `LAH` it would give achiral compound `( E)`. (ii) `(B)` id `(IV)`, since ETHERS are inert to OXIDATION. (iii) Iosoform test is SHOWN by `(II)`, so `(C)` is `(II)`. (iv) .