From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants: (i) 3NO(g) to N_(2)O(g), "Rate"=k[NO]^(2) (ii) H_(2)O_(2)(aq)+3I^(-)(aq)+2H^(+) to 2H_(2)O(l)+I_(3)^(-), "Rate"=k[H_(2)O_(2)][I^(-)] (iii) CH_(3)CHO(g) to CH_(4)(g)+CO(g) , "Rate"=k[CH_(3)CHO]^(3//2) (iv) C_(2)H_(5)Cl(g) to C_(2)H_(4)(g)+HCl (g) , "Rate"=k[C_(2)H_(5)Cl]

From the rate expression for the following reactions, determine their

1.	From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants: (i) 3NO(g) to N_(2)O(g), "Rate"=k[NO]^(2) (ii) H_(2)O_(2)(aq)+3I^(-)(aq)+2H^(+) to 2H_(2)O(l)+I_(3)^(-), "Rate"=k[H_(2)O_(2)][I^(-)] (iii) CH_(3)CHO(g) to CH_(4)(g)+CO(g) , "Rate"=k[CH_(3)CHO]^(3//2) (iv) C_(2)H_(5)Cl(g) to C_(2)H_(4)(g)+HCl (g) , "Rate"=k[C_(2)H_(5)Cl]
Answer» SOLUTION : (i) Order = 2, Dimensions of `K=("Rate")/([NO]^(2))=("mol L"^(-1)s^(-1))/(("mol L"^(-1))^(2))="L mol"^(-1)s^(-1)` (ii) Order = 2, Dimensions of k = Same as in (i) (iii) Order `=(3)/(2)`, Dimensions of `k=("Rate")/([CH_(3)CHO]^(3//2))=("mol L"^(-1)s^(-1))/(("mol L"^(-1))^(3//2))=L^(1//2)"mol"^(-1//2)s^(-1)` (iv) Order = 1, Dimensions of `k=("Rate")/([C_(2)H_(5)CL])=("mol L"^(-1)s^(-1))/("mol L"^(-1))=s^(-1)`.