1.

Give chemical tests to distinguish between the following pairs of compunds : (i) Ethanal and Propanal(ii) Phenol and Benzoic acid

Answer»

Solution :(i) ETHANAL and Propanal `:` Ethanal `( CH_(3) CHO ) ` and propanal `( CH_(3)CH_(2)CHO)` can be distinguished by performing iodoform test. Ethanal gives a yellow precipitate of `CHI_(3)` while propanal does not REACT.
`CH_(3) CHO OVERSET( NaOH ) ( rarr) HCOONa + CHI_(3)`
(ii) Phenol and Benzoic acid `:` Benzoic acid gives an effervescence with a solution of sodium hydrogen carbonate while phenol shows no ACTION.


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