1.

Give the reactions of nitrous acid with primary secondary and tertiary amines.. (b) Name the products with chemical reactions when the following compounds are hydrolysed: (i) CH_(3)CJH_(2)CN woth dil. HCl (ii) CH_(3)CN with alkaline H_(2)O_(2) (iii) C_(2)H_(5)NC with di. HCl (iv) C_(2)H_(5)NO_(2) with dil. HCl (c ) Explain the formation of the mixture of (i) PhCH_(2)CHO and (ii) PhCOMePh(CHOH)CH_(2)NH_(2) (A) is treated with nitrous acid (d) How nitrobenzene is identified by using Mulliken-Baker test?

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