1.

[H=1, C=12,O=16, Na=23, P=31,S=32] {:("Column-I","Column-II"),((A)4.1 g H_2SO_3,(p)"200 ml of 0.5 N NaOH is used forcomplete neutralization"),((B)4.9 g H_3PO_4,(q)"200 millimoles of oxygen atoms"),((C )4.5 g "oxalic acid"(H_2C_2O_4),(r)"Central atom has its highest oxidation number"),((D)4.3 g Na_2CO_3,(s)"May react with an oxidising agent"),(,(t)"Shape around central atom is regular"):}

Answer»

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SOLUTION :(A)4.1 gm =`4.1/82` mole `H_2SO_3`=50 m mole
2NaOH+`H_2SO_3toNa_2SO_3+2H_2O`
m moles of NaOH requries =2 x m mole of `H_2SO_3`
=100
=m mole of NaOH present (200 ml x 0.5 N)
HIGHEST O.N. of S= +6
(B)`4.9 gm =4.9/98` mole =50 m mole of `H_3PO_4` =200 m mole 'O' atom
Highest O.N. of P = +5
(C )4.5 gm =`4.5/90` =50 m mole `H_2C_2O_4` (di basic acid)
m mole of NaOH requires =2 x 50 =100
Highest O.N. of C = +4
(D)5.3 gm =`1/20` mole `Na_2CO_3` It do not reacts with NaOH and m mole of O atom =`1/20xx1000xx3=150`


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