1.

H_2 S in the presence of HCl precipitate II group but not IV group because

Answer»

HCl activates `H_2 S`
HCl increases CONCENTRATION of CI
HCI decreases concentration of `S^2`
HCI lowers the SOLUBILITY of `H_2 S` in solution.

Solution :Due to COMMON ion effect , HCl decreases concentration of `S^(2-)` ions and only II group basic radicals are precipitated.


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