1.

How are SO_(2)Cl_(2) and SO_(2) obtained from sulphuric acid ?

Answer»

Solution :`SO_(2)Cl_(2)` is FORMED from `H_(2)SO_(4)` by treating with excess of phosphorus PENTACHLORIDE.
`H_(2)SO_(4)+2PCl_(5)rarrSO_(2)Cl_(2)+2HCl+2POCl_(3)`
`SO_(2)` is OBTAINED from `H_(2)SO_(4)` when heated with copper METAL.
`2H_(2)SO_(4)+Cu rarr CuSO_(4)+2H_(2)O+2SO_(2)`


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