1.

How does anisole react with methyl chloride?

Answer»

SOLUTION :(a) Mechanism INVOLVES THREE steps
Steps 1. FORMATION of protonated ALCOHOL :
Alcohols react with sulphuric acid to form protonated alcohol.

Step - 2 :Formation of Carbocation :
The protonated alcohol loses a molecule of water to form ethyl carbocation.

Step 3 : Formation of ethene by elimination of a proton :
The carbocation loses a proton to form ethene.

(b) Anisole undergoes Friedal crafts reactions with methyl chloride in presence of anhydrous aluminium chloride. Methyl groups are introduced at ortho and para positions.


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