1.

How ionic radii varies along the group and period. Calculate the effective nuclear charge experienced by the 4s electron inpotassium atom

Answer»

1)The ionic radii increases down the group and decreases across a period2)Zeff = Z - S where Z is the nuclear charge (19 for K) and s is the screening of the nuclear charge by all the other e⁻. S is calculated by Slater's Rules[1s^2] [2s^2 2p^6] [3s^2 3p^6] [4s^1]S for 4s = 2 + (8×1.0) + (8×0.85) = 16.8Zeff = 19 - 16.8 = 2.2



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