1.

How long a current of 3 amp has to be passed through a solution of AgNO_(3) to coat a metal surface of 80 cm^(2) with 0.005 mm thick layer ? Density of Ag is 10.5 g//cm^(3).

Answer»

Solution :No. of eq. of Ag deposited
`= ("wt. of Ag deposited in grams")/("equivalent wt. of Ag")`
`= ("volume " xx " density")/("equivalent weight")`
`= ("surface area " xx " thickness " xx " density")/("equivalent weight")`
`= (80 xx 0.0005 xx 10.5)/(108)`
`= (7)/(1800) = 0.0039`
Mole of ELECTRIC charge = 0.0039 FARADAY
`= 0.0039 xx 96500` coulombs
376.35 coulombs.
`THEREFORE` duration of electrolysis `= ("charge in coulombs")/("current in amp")`
`= (376.35)/(3)s`
`~~ 125s`.


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