1.

How will you convert dietylamine into (i) N,N-diethylacetamide (ii) N-nitrosodiethylamine

Answer»

Solution :(i) Conversion of diethylamine into N,N-diethylacetamide
`underset(("diethylamine")("Acetyl chloride"))((C_(2)H_(5))_(2)NH+CH_(3)COCl) overset("PYRIDINE")(to)underset((N,N-diethyl acetamide"))(C_(2)H_(5))_(2)N-CO-CH_(3)+HCL`
diethylamine react with acetylchloride in the presence of pyridine to form N,N-deithyl acetamide.
(ii) Conversion of diethylamine into N- NITROSODIETHYLAMINE:
`underset(("Diethylamine"))((C_(2)H_(5))_(2)NH) underset(("or")HNO_(2))overset(NaNO_(2)//Conc.HCl)(to) underset(N-"nitrosodiethylamine")((C_(2)H_(5))_(2)N-N=O`
Diethylamine react with nitrous acid to give N-nitrosodiethylamine.


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