1.

How will you distinguish betweeen: (b) CH_(3)-underset(CH_(3))underset(|)(N)-H and (C_(3))_(3)N

Answer»

Solution :a. By reacting with `NaNO_(2)` and HCl at the TEMPERATURE of aroudn to `5^(@)C`, Aniline will from diazonium sal. `CH_(3)NH_(2)` will form methanol and bubbles of `N_(2)` GAS will COME out of the solution.
b. By Hinsberg.s reagent `C_(6)H_(5)SO_(2)Cl(CH_(3))_(3)N` will not react. `(CH_(3))_(2)NH` form a product which is insoluble in alkali.


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