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How will you distinguish between the following isomer pairs ? (a) (i) [Cr(H_(2)O)_(6)]Cl_(3) and (ii) [Cr(H_(2)O)_(5)Cl]Cl_(2)H_(2)O (b) (i) cis [Pt (NH_(3))_(2)Cl_(2)] and (ii) trans [Pt(NH_(3))_(2)Cl_(2)] (c ) The two enantiomers of [CoCl_(2)(en)_(2)]^(+) |
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Answer» Solution :(a) The water molecules in isomer (i) are not lost EASILY, being coordinated to the central atom WHEREAS the water molecule in isomer (ii) is lost easily on HEATING. (B) CIS isomer is dextro-rotatory whereasthe other is laevo-rotatory. |
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