1.

How will you manufacture sulphuric acid by contact process?

Answer»

Solution :Manufacture of sulphuric acid by contact process involves the following steps.
i. INITIALLY SULPHUR dioxide is produced by burning sulphur or iron pyrites in oxygen/air.
`S+O_(2)rarrSO_(2)`
`4FeS_(2)+11O_(2)rarr 2Fe_(2)O_(3)+8SO_(2)`
ii. Sulphur dioxide formed is oxidised to sulphur trioxide by air in the presence of a catalyst such as `V_(2)O_(5)` or platinised ASBESTOS.
(iii) The sulphur trioxide is absorbed in concentrated sulphuric acid and produces oleum `(H_(2)S_(2)O_(7))`. the oleum is converted into sulphuric acid by diluting it with water.
`SO_(3)+H_(2)SO_(4)rarr H_(2)S_(2)O_(7)overset(H_(2)O)rarr 2H_(2)SO_(4)`
To MAXIMISE the yield the plant is operated at 2 bar pressure and 720 K. The sulphuric acid obtained in this process is over `96%` pure.


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