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How would you account for the fact that the transition metals and their compounds are found to be good catalysts in many processes ? |
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Answer» Solution :According to activated complex theory ( intermediate compound formation theory ), DUE to variable oxidationstates, transition metal combines with THEREACTANT `//`s to forma an intermediate ( an UNSTABLE species ) called activated complex whichi finally decomposes to form the products regenerating the catalyst. `underset("Reactant")(A) + underset("catalyst")(C) rarr underset("(Intermediate)")underset("Activated complex")([AC]) rarr underset("Product")(B) + underset("Catalyst")(C)` The REACTION proceeds through a new path with lower activation energy and hence is faster. According to adsorption theory, transition metal provides a large surface are with free valencies on which the reactants are adsorbed. As a result , the concentration of the reactants on the surface increases and hence the rate increases. |
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