1.

(i) A yellow precipiate of the compound A is formed on passing H_(2)S through a neutral solution of the salt B. (ii) The compound A is soluble in hot dilute HNO_(3) but insoluble in yellow ammonium sulhpide. (iii) The The solution of B, on treatment with a small quantitity of NH_(3), gives a white precipitate soluble in an excess of the reagent, forming a compound C. (iv). The solution of B gives a white precipitate with a small concentration of KCN. the precipitate is soluble in an excess of the reagent, forming a compound D. (v) the solution of D, on treatment with H_(2)S, gives A. (vi) The solution of B in dilute HCl, on treatment with a solution of BaCl_(2), gives a white precipitate of the compound E, which is almost insoluble in concentrated HNO_(3). Q. Which of the following are the white precipitate and the soluble substance formed by the excess of the KCN reagent. respectively, in (iv) ?

Answer»

`As(CN)_(3) and[As(CN)_(6)]^(2-)`
`SN(CN)_(3) and [Sb(CN)_(6)]^(3-)`
`Zn(CN)_(2) and [Zn(CN)_(4)]^(2-)`
`CD(CN)_(2) and [Cd(CN)_(4)]^(2-)`

ANSWER :D


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