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(i) An aqueous solution of a compound A is acidic towards litmus and A sublimes at about 300^(@)C (ii)A solution of A, on treatment with an excess of NH_(4)SCN, gives a red compound, and on treatment with a solution of K_(4)[Fe(CN)_(6)], gives a blue compound. (iii) The solid A, on being heated with an excess of K_(2)Cr_(2)O_(7) in the presence of concentrated H_(2)SO_(4), evolves deep red vapours of D. (iv) On passing the vapours of D into a solution of NaOH and then adding the solution of acetic acid and lead acetate, a yellow precipitate of a compound E is obtained. Q. Can compound A be prepared in the anhydrous form by strongly heating its hydrated crystals? |
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Answer» No, because the WATER molecules are very stongly bound in the hydrated crystals |
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