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(i) What type of isomerism is shown by the complex [Cr(H_(2)O)_(6)]Cl_(3)? (ii) On the basis of crystal field theory, write the electronic configuration for d^(4) ion if Delta_(0)gtP. (iii) Write the hybridization and shape of [CoF_(6)]^(3-). (Atomic number of Co=27) |
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Answer» SOLUTION :(i) Solvate Isomerism. (ii) `[Cr(H_(2)O)_(6)]Cl_(3)` Violet `[Cr(H_(2)O)_(5)CL]Cl_(2)-H_(2)O` (Blue green) `[Cr(H_(2)O)_(4)Cl_(2)]Cl. 2H_(2)O` Dark green (iii) `[CoF_(6)]^(3-)` is an outer orbital or HIGH spin complex involving `Sp^(3)d^(2)` hybridisation and octahedrol shape. |
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