1.

Identify B

Answer»

`FeCI_(2)`
`NiCI_(2)`
`ZnCI_(2)`
`FeCI_(3)`

Solution :Zinc oxide turns yellow on heating and white on COOLING. (A) is `ZnO`, which is not soluble in water. `ZnO` is called Chinese white, ZINCITE, philosopher's wool.
`ZnO +2HCI rarr UNDERSET((B))(ZnCI_(2)) +H_(2)O`
`ZnO +2NaOH rarr underset((C))(Na_(2)ZnO_(2))+H_(2)O`
`ZnO` is amphoteric.
`underset((B))(ZnCI_(2))+H_(2)S rarr` No ppt.
This is because `ZNS` is precipitated in basic MEDIUM with sufficient `[S^(2-)]` concentration.
`underset(("Neutral or basic solution"))(ZnCI_(2)+H_(2)S) overset(NH_(4)OH)rarr underset((D))(ZnSdarr) +2HCI`


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