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Answer» At absolute zero temperature, the entropy of all CRYSTALLINE substances is not taken to be zero At absolute zero temperature, the entropy of a PERFECTLY crystalline SUBSTANCE is positive. At absolute zero temperature, entropy of a perfectly crystalline substance is taken to be zero. At `0^@C` , the entropy of a perfectly crystalline substance is taken to be zero. Solution : This is the statement of third law of thermodynamics. In a perfect crystal, at absolute zero temperature, each constituent of LATTICE must have the lowest energy, so it LEADS to perfect order, therefore, zero entropy.
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