1.

Identify the major product obtained on monobromination (Br_2//FeBr_3) of meta-methylanisole and accout for its formation.

Answer»

SOLUTION :
Both `-CH_3 and -OCH_3` are o-/p-directing GROUPS.
THEREFORE the possible positions of attack which are facilatated by these group are indicated by arrown as shown below .

Attack by the electrophile `(Br^+)` is disfavoured `C_2` because this position is most CROWDED. Again. -I effect of `-OCH_3`group does not favourattack at `C_6` . so most favourable attack occurs at `C_4` , thereby PRODUCING 4-bromo-3-methylanisole as the majorproduct.


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