1.

If 772 mL of SO_(2) gas at STP is adsorbed on 2 g of charcoal at an equlibrium pressure of 16 atmospheres and the value of the constant 'k' in the Freundlich equation is 0.48. the value of the constant 'n' will be

Answer»


Solution :Molar mass of `SO_(2)=64 G mol^(-1)`
Moar volume at `STP=22400mL`
`THEREFORE` ML of `SO_(2)` at STP well have mass
`=(64)/(22400)xx772=1.92g`
`therefore x/m=(1.92)/(2)=0.96`
But `x/m=kP^(1//n)`
`therefore 0.96 =0.48 xx(16)^(1//n) or 2=(16)^(1//n)`
`therefore n=4.`


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