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If the boundary of system moves by an infinitiesimal amount, the work involved is given by dw= -P_("ext") dV, for irreversible process W= -P_("ext") Delta V (where DeltaV= V_(f)- V_(i)). For reversible process P_("ext") = P_("int") +- dP ~~ P_("int"), so for reversible isothermal process W= -nRTln (V_(f))/(V_(i)). 2 mole of an ideal gas undergoes isothermal compression along three different paths: (i) reversible compression from P_(i)= 2 bar and V_(i)= 8 to P_(f)=20 bar (ii) a single stage compression against a constant external pressure of 20 bar (iii) a two stage compression consisting initially of compression against a constant external pressure of 10 bar until P_("gas") = P_("ext"), followed by compression against a constant pressure of 20 bar until P_("gas") = P_("ext"). Total work done on the gas in two stage compression is |
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Answer» 40 |
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