1.

In a mixture of closely related liquids (such as benzene and toluence), the Roult's law states that theratio P_(A) is proportional to the mole fraction of A in the liquid, P_(A)x_(A). Mixtures that obey the law throughout thecomposition ranges from pure A to pure B are called ideal solutions . In ideal solution thesolute also obeys Roult's law . Then the total pressure is given by P_("total")=P_(A)^(0)x_(A)+P_(B)^(0)x_(B) Each of the followingsolution obeys Raoult's law except

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n-hexane +n-heptane
Methanol+Ethanol
carbon tetrachloride+carbon disulphide
chloroform+Acetone

Answer :D


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